S,S-Diphenyl-S-pyrrolidinoiminosulfonium perchlorate
نویسندگان
چکیده
منابع مشابه
4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium perchlorate
In the title compound, C(22)H(19)N(2) (+)·ClO(4) (-), the three pendant aromatic rings are twisted from the plane of the imidazolium ring by dihedral angles of 17.3 (2), 65.7 (2) and 3.4 (2)°. In the crystal structure, N-H⋯O and N-H⋯(O,O) hydrogen bonds link the ions, forming a ribbon-like structure along the a axis.
متن کاملDiphenyl [(S)-1-phenylpropanamido]phosphate
The title compound, C(21)H(22)NO(3)P, was synthesized from the reaction of (C(6)H(5)O)(2)P(O)(Cl) and S-1-phenyl-propyl-amine (1:2 mole ratio) at 273 K, followed by removal of the S-1-phenyl-propyl-amine hydro-chloride by-product by dissolving in H(2)O. The P atom is located in a distorted tetra-hedral environment. The bond angles at the P atom vary from 99.51 (12) to 116.68 (12)°. The sp(2) ch...
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Commercial interest in perchlorates began in the late 1890s/early 1900s in Europe and the United States as a direct result of the pioneering efforts in rockets and their propulsion systems (Mendiratta et al. 1996). The production of ammonium perchlorate, the largest component of solid rocket propellants, far outpaced that of the other perchlorates listed in Table 4-1. Their commercial manufactu...
متن کامل{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
In title complex, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·1.5H(2)O, the Co(III) ion is in a slightly distorted octa-hedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water mol-ecules and all components are connected via inter-molecular O-H⋯O hydrogen bonds.
متن کاملDimethyl 3,3′-diphenyl-2,2′-[(S)-thiophene-2,5-diylbis(carbonylazanediyl)]dipropanoate
The asymmetric unit of the title compound, C(26)H(26)N(2)O(6)S, contains two independent mol-ecules; each has twofold symmetry with the S atom and the mid-point of the C-C bond of the thio-phene ring located on a twofold rotation axis. In the two mol-ecules, the terminal benzene rings are oriented at dihedral angles of 65.8 (3) and 63.5 (3)° with respect to the central thio-phene rings. The met...
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ژورنال
عنوان ژورنال: IUCrData
سال: 2017
ISSN: 2414-3146
DOI: 10.1107/s2414314617012512